I've been searching for ages for a good multi-room audio solution using raspberry pi and I've finally found one!
Logitech Media Center (squeeze server) running on either a server, nas or raspberry pi (anything that's always on)
http://www.mysqueezebox.com/downloadInstall
SqueezePlug image onto each raspberry pi you want to be a media player (each room of your multi-room system). This image supports wifi dongles out of the box and is designed to run headless. Most importantly it comes pre installed with SqueezeSlave!
I've installed Squeezebox Remote onto my android phone and i'm away, I can select any source (internet radio, media files, iTunes, lastFM etc etc etc) and play to any location or multiple locations that I have a raspbpi!
Awesome and really easy to setup. Ultra cheap mutli-room audio!